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The high-pressure behaviour of a synthetic P21/c ferrian magnesian spodumene, M2 (Li0.85Mg0.09Fe2+ 0.06)M1(Fe3+ 0.85Mg0.15)Si2O6, has been investigated using in situ single-crystal X-ray diffraction and Raman spectroscopy. No phase transition has been observed within the pressure range investigated. The isothermal equation of state up to 7 GPa was determined. V0, KT0 and K, simultaneously refined with a Murnaghan equation of state, are: V0= 415.66(7) Å3, KT0=83(1) GPa and K=9.6(6). The magnitudes of the principal unit-strain coefficients were calculated and their ratios 1:2:3=1.00:1.85:2.81 at P=6.83 GPa indicate a very strong anisotropy. Monitoring of the intensity of b-type reflections (h+k= 2n+1) confirms that from room conditions up to 7 GPa the primitive lattice is maintained. Raman spectra have been collected up to 7.4 GPa. No change in the number of observed vibrational modes occurs in the pressure range investigated. At high frequency, the Raman doublet relative to the Si–O–Si vibrations of the two distinct tetrahedral chains is a broad band at room pressure, however, the frequency difference between the two modes increases with increasing pressure.Operating system: Windows NT  相似文献   
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The volume variation as a function of pressure along the jadeite–aegirine solid solution was determined at room temperature up to pressures between 6.5 and 9.7 GPa by single-crystal X-ray diffraction. The unit-cell volumes collected at room pressure for the different compositions indicate a slight deviation from linearity along the join. The pressure–volume data have been fitted using a third-order Birch-Murnaghan equation of state (BM3-EoS). The bulk modulus, K T0, varies from 134.0(7) GPa for pure jadeite to 116.1(5) GPa for pure aegirine. Its evolution with composition along the join is not linear and can be described by the following second order polynomial:
(1)
The value of the first pressure derivative K′ is close to 4 for all the samples investigated and can be used in a BM3-EoS to determine the volume variations of these pyroxenes up to 7–10 GPa. Along the join the highest compressibility among the crystallographic directions is always observed along a, however, the compression along b is the most affected by compositional changes. The strain ellipsoid analysis indicates that the major compression occurs on the (0 1 0) plane along a direction at about 145° to the c axis (from c to a). The anisotropy of the compression increases with increasing the aegirine component, as confirmed by the analysis of both the axial compressibility and the strain tensor.  相似文献   
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The design of a pump and treat (P&T) system for the hydraulic control of a contaminated plume in a confined aquifer is presented here. Being the system designed for the emergency containment of a nonaqueous phase liquid plume, the evaluation of the system’s short-term efficiency was considered an important issue. For this reason, both time-related and ultimate capture zones were defined. They were traced using the automatic protection area (APA) model, a capture-zone delineation tool based on a hybrid forward-backward particle tracking algorithm, that provides an automatic post-processing encirclement of capture zones. Two simple indexes are here proposed for the evaluation of the performance of the hydraulic barrier, that is, the efficacy and efficiency indexes, calculated from the capture areas provided by APA. The discharge rates of the wells were dimensioned applying the APA algorithm, maximizing efficacy and efficiency of the barrier. Results proved both visually (via plotting of capture zones) and numerically (via calculation of the indexes) that the P&T system can provide a complete capture of the contaminated area and minimizes the volume of extracted water. Consequently, the APA algorithm was proved to be a useful tool in capture zone delineation. As a future perspective, it could be coupled with the real-time measurement of pumping rates and water levels and be implemented as a part of a tuning tool for the management of the hydraulic barrier.  相似文献   
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The aim of this study is to apply an integrated approach to determine nitrate sources and fate in the alluvial aquifer of the River Vibrata (Abruzzi, central Italy) by coupling the Isotope and the Component approaches. Collected data include concentration and nitrogen isotope composition of groundwater samples from the alluvial aquifer and nitrogen loads arising from agricultural and non-agricultural sources. The adopted methodology identified synthetic fertilizers as main sources of nitrate in the Vibrata alluvial aquifer. At the catchment scale, two different zones have been identified: the Upper Valley, where infiltration to groundwater is dominant and nitrogen easily migrates into the aquifer; in this area, nitrate content in groundwater is stable and normally higher than EU requirements. Moreover, streamwaters are fed by groundwater with a nitrate content likely lowered by denitrification processes occurring in the hyporheic zone. In the Lower Valley, runoff processes dominate and the nitrate content in surface waters is higher. Nevertheless, groundwater is locally affected by denitrification that breaks down the nitrate content, which often reaches values consistent with law limits.  相似文献   
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Intense blooms of the benthic dinoflagellate Ostreopsis cf. ovata have occurred in the northern Adriatic Sea since 2006. These blooms are associated with noxious effects on human health and with the mortality of benthic organisms because of the production of palytoxin-like compounds. The O. cf. ovata bloom and its relationships with nutrient concentrations at two stations on the Conero Riviera (northern Adriatic Sea) were investigated in the summer of 2009. O. cf. ovata developed from August to November, with the highest abundances in September (1.3 × 106 cells g−1 fw corresponding to 63.8 × 103 cells cm−2). The presence of the single O. cf. ovata genotype was confirmed by a PCR assay. Bloom developed when the seawater temperature was decreasing. Nutrient concentrations did not seem to affect bloom dynamics. Toxin analysis performed by high resolution liquid chromatography-mass spectrometry revealed a high total toxin content (up to 75 pg cell−1), including putative palytoxin and all the ovatoxins known so far.  相似文献   
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In June 2000, two Mw6.5 earthquakes occurred within a 4-day interval in the largest agricultural region of Iceland causing substantial damage and no loss of life. The distance between the earthquake epicentres and the fault rupture was approximately 15 km. Nearly 5000 low-rise residential buildings were affected, some of which were located between the faults and exposed to strong ground motion from both events. The post-earthquakes damage and repair costs for every residential building in the epicentral region were assessed for insurance purposes. The database is detailed and complete for the whole region and represents one of the best quality post-earthquake vulnerability datasets used for seismic loss estimation. Nonetheless, the construction of vulnerability curves from this database is hampered by the fact that the loss values represent the cumulative damage from two sequential earthquakes in some areas, and single earthquakes in others. A novel methodology based on beta regression is proposed here in order to define the geographical limits on areas where buildings sustained cumulative damage and predict the seismic losses for future sequence of events in each area. The results show that the average building loss in areas affected by a single event is below 10% of the building replacement value, whilst this increases to an average of 25% in areas affected by the two earthquakes. The proposed methodology can be used to empirically assess the vulnerability in other areas which experienced sequence of events such as Emilia-Romagna (Italy) in 2012.  相似文献   
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We have performed deep searches for radio pulsations from four southern anomalous X-ray pulsars (AXPs) to investigate their physical nature in comparison with the rotation powered pulsars. The data were acquired using the Parkes radio telescope with the 1.4 GHz multibeam receiver. No pulsed emission with periodicity matching the X-ray ephemeris have been found in the observed targets down to a limit of ∼0.1 mJy. A blind search has also been performed on all the 13 beams of the multibeam receiver (the central beam being pointed on the target AXP), leading to the serendipitous discovery of two new radio pulsars and to the further detection of 18 pulsars. Also a search for single dispersed pulses has been performed in the aim to detect signals similar to those of the recently discovered rotating radio transients.   相似文献   
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